2-[Tris(pyridin-2-yl)methyl]pyridiniumtrans-bis(acetonitrile)tetrachloridoruthenate(III) acetonitrile monosolvate
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چکیده
منابع مشابه
2-(Pyridin-2-ylamino)pyridinium thiocyanate acetonitrile monosolvate
The title compound, C(10)H(10)N(3) (+)·NCS(-)·CH(3)CN, is the acetonitrile solvate of the thio-cyanate salt of protonated dipyridin-2-yl-amine. Protonation occurs at one of the pyridine N atoms. The mol-ecular geometry around the central N atom is essentially planar (sum of angles = 359.89°). In the crystal, N-H⋯N hydrogen bonds, as well as C-H⋯S contacts link the different residues into chains...
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In the title compound, [Co(2)(C(7)H(8)NO)(3)(N(3))(3)]·CH(3)CN, the two Co(II) ions in the dinuclear complex have different coordination environments, both in a distorted octa-hedral geometry. One Co(II) atom is coordinated by three O atoms from the three 2-hy-droxy-ethyl-pyridine (HEP) bridging ligands, two N atoms from two HEP ligands and one azido ligand, while the other Co(II) atom is coord...
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In the hydrazone molecule of the title compound, C(13)H(9)I(2)N(3)O(2)·CH(3)CN, the aromatic rings form a dihedral angle of 9.4 (3)°. In the crystal structure, inter-molecular I⋯N inter-actions [3.099 (4) Å] link hydrogen-bonded aggregates of the hydrozone and solvent molecules related by translation along the b axis into chains. An intramolecular O-H⋯N hydrogen bond forms an S(6) ring.
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In the crystal structure of the title compound, C(9)H(7)BrN(4)OS·C(2)H(3)N, the mol-ecules are connected via N-H⋯O and N-H⋯S inter-actions into zigzag chains perpendicular to [001]. The mol-ecules in these chains are additionally linked to acetonitrile solvent mol-ecules through N-H⋯N hydrogen bonding. The mol-ecules are arranged in layers and are stacked in the direction of the c axis indicati...
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ژورنال
عنوان ژورنال: IUCrData
سال: 2017
ISSN: 2414-3146
DOI: 10.1107/s2414314617013712